I don't have any references to back this up...but, I would go with the higher memory clock, ie FSB=100. The memory kick might improve your overall performance more than the jump from 450 to 533 would.
Now, before you stop, are you sure that the Cel 533 (FSB=66) will not overclock to 800, ( ie FSB=100). Most of them will come close. Give it a try before you settle for 450 or 533.