32bit 33 mhz as noted theoretical max 133MB/s
64 bit 33 mhz, 266MB/s
64 bit 66 mhz, 512MB/s
guess what
32bit 66mhz, also 266MB/s (hey, i didn't even know these existed, but promise makes a 4 channel ata raid controller that is 32bit, 66mhz for mb's that will support it.
practically speaking, i think the peak bandwidth across a 32 bit, 33mhz pci is around 120's