Gryfon,
I'm an old school Overclocker, high PCI bus is par for the course. As I type this, my PCI bus is at 43.5 Mhz. It hasn't gone under 42 Mhz PCI for two and a half years.
My complete hardware list is:
Mobo: Abit KR7A-133, without mods (CX BIOS)
Processor: AUIHB 0302 XP-2100+ cut and painted to 1.85v, and 13.5x multiplier.
Cooling for Processor: Lapped Alpha PAL 8045 with 40 CFM reverse flowing fan.
HDD: 2 x 80 GB Maxtor DiamondMAx Plus 9 (6Y080P0).
RAM: Kingston HyperX PC2700 512 MB.
Video: Gainward Golden Sample Ti-4200 128mb, with complete Coolbits hack for overclocking. No harware mods.
Cooling for video: Thermaltake copper GF4 cooler with 60 mm reverse flow fan.
CD: Lite-On 52327S (QS0C), and 40125S (overclocked with XSU1 from a 32123S)
All hardware listed has been Prime95 tested at 50 Mhz PCI for thirteen hours (blend test) without errors.
The naysayers abound. They first said that I couldn't do it safely. Then they said that I would burn it all up, then they said I would corrupt the data, now they day it kills the hardware too fast (as if I still want this hardware in five years). I have no doubt that all items listed will run for another 2.5 years if I want them to. It's not necessary to have special skills, special tools, or even special hardware. Just good quality base parts, a notebook, and a couple of extra case fans to start with. As you progress, then a better CPU HS/Fan combo.
Take your time, read up on your hardware, and monitor temperatures as you raise the FSB.
Good Luck!
Mark