Originally posted by: AndyHui
Strictly speaking, Windows NT is older than Windows 95. Windows 95 was a hybrid 16-bit/32-bit OS.
If you want to be even more picky, Windows 3.11 had the Win32S DLLs for limited 32-bit support.
As far as Windows itself goes, probably not much difference. The greatest difference is the ability to flat address more than 4GB of RAM.
Otherwise, please read the FAQ: The myths and realities of 64-bit computing.