Higher rated PSUs have more amps, not higher voltages (which are always 3.3V, 5V, 12V etc.). It is however possible for the voltages to drop if you push the PSU too hard (ie. your computer components draw too much current).
Like a lamp. If you remove it from a 10 Amp circuit and plug it into a 20 Amp circuit it doesn't get brighter. Power isn't "pushed" to the load. The load "draws" the power.
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