Wanna see Galvanic Corrosion?

Zebo

Elite Member
Jul 29, 2001
39,398
19
81
two years old block in a 24/7 box Link

I've been warning people not to mix annodized aluminum and copper due to galvanic corrosion - the best blocks are either all copper like MCW 6000/6002, Delrin/Copper or Acetal/copper combo. Plastics have thier own problem though- thermal cycling - which will crack overtime thus the former two options are best. Good luck.
 

Zap

Elite Member
Oct 13, 1999
22,377
7
81
LOL, and here I was expecting to see a pic of Galvanized Yankee with a sunburn. :laugh:
 

GalvanizedYankee

Diamond Member
Oct 27, 2003
6,986
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Originally posted by: Zap
LOL, and here I was expecting to see a pic of Galvanized Yankee with a sunburn. :laugh:

Zap, I'm so white that I can't tan :) Really! My corrosion is lots of gray hair.

Zebo, was the coolent ever changed in the two year period? Do you ever check the coolent's ph?
Like with litmus(sp) paper.

The anodizing most of us see is decorative in nature. It's purpose is to reduce scuff marks, stop atmospheric corrosion and hold color. What it is, is a very thin porous layer of glass.
Industrial anodizing is not that more expensive a process and can be up to .003"thick. Decorative is .0005"thick.
The point is, if this stuff was industrial anodized, it would be inert.


...Galvanized=A self healing zinc plating used on steel and iron for protecting the base metal from corrosion.


 

Greenman

Lifer
Oct 15, 1999
21,863
6,239
136
To be honest, that block looks fine to me. In the plumbing around my part of the world water quality is not that good, and most copper plumbing shows minor discoloration/deposits. I'd say that block has at least 5 more years of use in it.
 

Howard

Lifer
Oct 14, 1999
47,982
11
81
Originally posted by: GalvanizedYankee
Originally posted by: Zap
LOL, and here I was expecting to see a pic of Galvanized Yankee with a sunburn. :laugh:

Zap, I'm so white that I can't tan :) Really! My corrosion is lots of gray hair.

Zebo, was the coolent ever changed in the two year period? Do you ever check the coolent's ph?
Like with litmus(sp) paper.

The anodizing most of us see is decorative in nature. It's purpose is to reduce scuff marks, stop atmospheric corrosion and hold color. What it is, is a very thin porous layer of glass.
Industrial anodizing is not that more expensive a process and can be up to .003"thick. Decorative is .0005"thick.
The point is, if this stuff was industrial anodized, it would be inert.


...Galvanized=A self healing zinc plating used on steel and iron for protecting the base metal from corrosion.
I think it's a ceramic, not a glass.
 

Zap

Elite Member
Oct 13, 1999
22,377
7
81
Originally posted by: GalvanizedYankee
Originally posted by: Zap
LOL, and here I was expecting to see a pic of Galvanized Yankee with a sunburn. :laugh:

Zap, I'm so white that I can't tan :) Really!

That's exactly it, a sunburn. Sorry for my amusement at your expense - if you were here you'd be amused at my expense because when I thought of it I was giggling like a little girl with a secret. :D Picture that and we'd be even.

On second thought, don't picture that.:eek:
 

GalvanizedYankee

Diamond Member
Oct 27, 2003
6,986
0
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Your thinking on this is wrong Howard. I make a real effort not to pull comments out of my...You know. Plz do like wise.
Some of the common elements alloyed with aluminum include copper, manganese, *silicon*, magnesium and zinc.

When aluminum is anodized the process causes a deplating action to take place leaving the *silicon* on the surface. This is more closly related to glass rather than ceramic, by a long shot ;) This glass, when produced by *hard*anodizing is very thick and is an insulator of heat and electricity.
If the aluminum being anodized has a high concentration of any of the above alloying elements, aside from silicon, the part will be removed from the solution, cleaned of the alloy's oxide, then reintroduced to the solution.

For an explaination in layman's terms of the anodizing process look around this link. Be sure to read the anodizing forums at this site.
At the very least scroll down to mid-page and look at the micro-pic of the silicon structure.

http://www.caswellplating.com/kits/aluminum.htm


...Galvanized
 

Howard

Lifer
Oct 14, 1999
47,982
11
81
Howard, it's silicon and the deplating process leaves silica on the surface.
I have never heard anything like this. Your first link didn't contradict what I'd thought either. A Ctrl-F for "silicon" leads me to something called Aluminum De-Oxidizer & De-Smut which removes unwanted substances from the to-be-anodized surface such as copper, silicon and magnesium.

I didn't find anything relevant to anodizing in that article you just linked.

This link says:
An oxide film can be grown on certain metals ? aluminum, niobium, tantalum, titanium, tungsten, zirconium ? by an electrochemical process called anodizing.
From the horse's mouth:
It is an electrochemical process that thickens and toughens the naturally occurring protective oxide.
 

Howard

Lifer
Oct 14, 1999
47,982
11
81
Come on, you can't tell me I'm pulling comments out of my ass and then not back up your claims.