I can confirm what techfuzz is saying there - in both cases.
UDMA 100/133 are just the speeds that the hard drive can transfer information to and from the system. The thing is, no drive today is fast enough to sustain that speed, the very best dont even reach 60.
It's like this: imagine you drive a Lada that does 60mph tops. Driving on a city street, you are limited to 30mph, upgrading to a highway lets you reach the full potential of the car, because the speed limit is 65. Taking your Lada on the Autobahn will not speed up the car at all, because you are limited by the potential of the car, not the speed limit of the highway.