Well, the best way to learn is to experimentate, go into your BIOS and you should recognize some of the terms, the clockspeed of a proccesor is based on its FSB speed and its multiplier, in A64s the FSB is the result of multiplying the LTD & the HTT (hyper transport) I think. Just have Zebo's guide on hand and explore your BIOS settings, change a few settings, experiment and you'll become an OC buff in no time.
Always increase clocks in small increments and remember FSB and RAM speed have a symbiotic relation, this means the ram runs at the same speed as the FSB (1:1 ratio), thankfully you can use dividers to have fsb speeds be higher than ram speeds. Don't mess with voltage settings until you have a decent understanding of power and cooling. Try to find how much you can push the FSB, I have found its wise to keep the LDT at 3. ALWAYS check for stability, just because your computer can boot in a set frequency doesn't mean it will run stable, run Prime95, SuperPI and Memtest, those are great for checking OC stability and remember, in most of the cases a processor will reach its voltage limit first rather than its cooling limit.
Overclocking is more complex and more hard than what a guide may make it out to be and the best way to learn is by experience and the best thing to do when detecting OC instability causes is not to assume anything and not to discard any possibilities.
As a final tip, set yourself a goal and try to hit that and remember, your proccesor will not always oc the same as your neighbor's one, not even if they are the same proccesor.