Yes, assuming that the PSU is ATX. If it is AT, it requires a double pole single throw switch, you have to mess with 4 wires that way, a blue, white, black, and brown I believe. But on ATX PSU's, shorting the green wire and the black one adjacent to it does the trick. Make sure that the switch on the back of the PSU is set to on and it's plugged in, then hold the wire there for a couple seconds. You should at least see some sparks if the wire is conductive. Otherwise, PSU might be hosed.