It doesn't matter which black wire, they are all ground, but only touch the green and black together for a moment, thats what the Power On switch does. Having said this, the PS may still have 'issues', without a 'load' on the supply it may switch off or produce incorrect voltages. I'd just wait for the rest of your system to arrive. If you do a google search, you can find a fairly cheap power supply tester IIRC.