I have no real-world experience with either, but I was heavily leaning toward getting VX memory and did quite a bit of reading on the subject.
VX memory allows you (with sufficient vdimm, at least 3.4 volts) to run at 2225 timings at FSBs of 250 MHz and higher. TCCD won't achieve that combination of low timimgs and high FSB.
However, there's a question about whether running memory at such high vdimm can shorten CPU life. I have enough doubts now that I'll probably just go with TCCD.
Edit: I should also mention that running VX at high vdimm generates quite a lot of heat, which can create stability problems. Active cooling (a fan blowing directly on the memory) can help, but it just seems like another reason to avoid the issue altogether.