^ Yes an SSD is orders of magnitude faster than HDD, but the question was still which is faster for a particular use when you have two SSDs.
If the user isn't able to distinguish the difference then why are we talking about it? There are lots of areas in computing where the user can't distinguish the difference but then there's those pesky benchmarks that show a number and everyone wants to focus on that.
It seems almost as though you are assuming something rather than having ever tried it. Would you also argue that it doesn't matter if a single SSD alone is 50% faster than a different single SSD, because the slower one is so fast you won't notice the difference? If not, then why not also consider the potential a 2nd SSD /volume has for performance increases?
Your position doesn't make sense to me, it's as though you feel that things are so great we could never want more, even though it obviously will make a performance difference if you have file I/O going to two separate SSD vs one of the same. Again, how much of a difference depends on the specific scenario, but I think we can agree that the OS partition is going to be accessed practically every time you load a game or app, though it is still up to the individual how to split the files on each.
You also mentioned video editing. Do you feel it is faster reading from and writing to the same two drive array concurrently or reading from one SSD and writing to the other? It could go either way depending on the specifics.