I see no reason why it shouldn't work... If the drive is new and hasn't been formatted yet, that explains why Windows doesn't see it. As Administrator, right click on My Computer, click on Manage, and go down to the Disk Management. From there, you may get a convenient wizard, or you may just need to find the new drive in the list below, right click on it, and go from there (after initialization, you'll need to partition it and format the partition(s)).