The difference won't be much, nothing you would notice anyway. The 2 drives that stand to benefit the most, the 2 WD JB drives, unfortunately are not ATA133 drives. That being said, there is no reason not to go to with an ATA133 capable board, considering the price difference should be negligible. There are other benefits to ATA133 besides just potential increased throughput.
The reason IDE drives can't burst much over 80MB/s is interface overhead. Increasing potential bandwidth will increase burst rates. Unless IDE manufacturers found some unique 100MHz SDRAM that can't transfer data faster than 80MB/s.
"How about a person like myself who has multiple harddrives (currently I have 4),wouldn't the added bandwidth help?"
You won't see much either, unless you have 4 WD1200BB/JB or 4 IBM 120GXP's. The occurences where you are using more than one on a channel at full speed is probably not very often anyway. Currently, IDE drives just aren't fast enough for any of these limits to pose real caps on performance.