Your confusing megabytes/second with MHz.
And ATA66 controller can run at up to 66MB/sec.
The IDE bus is based off of the PCI bus, which on the KX133 runs at 33MHz 32bits for a peak theoretical transfer rate of 132MB/second. 32bits divided by 8 = 4 multiplied by MHz (33) for 132MB/second.
There is also 64bit and 66MHz PCI buses but those are primarily releaged to server boards.
The 132MB/second is shared among all of the PCI slots.
Also, you do not need any service pack to use the 4.29 Via 4in1 drivers, I use them under Win2k myself and they work beautifully.