Not totally positive on this, but Z68 boards need to have XMP memory and will only run in dual channel.
If Im not mistaken installing the triple channel kit would cause they memory to run in single channel which would reduce performance, it might run in dual channel if you pick up another 2GB stick. However, a dual channel 1600 mhz 8GB kit with tight timings and XMP is only $125, but a 1333 2GB stick of mushkin is only $20 so that may be the better option if you dont plan on ever needing 16GB and dont care that its not running at as high a speed.
Im pretty sure the effect of running non-XMP memory is that it will only be able to run at the lowest DDR3 speed but hell it might not work at all Im unclear on that. In the case that it runs at low speed you would probably get the 1333 you were wondering about