Not really, it's controller chip apparently is set to not enable the port until the host and device have completed a handshake. I have a 15$ Rosewill powered hub that will charge without having the computer on/connected.
I guess when you say you have a powered hub, it does connect to the wall outlet correct?
Short answer, yes.
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it is possible that not all hubs can do this. Apparently the one you have can't. But, are you sure? Have you used a VOM to check the port outputs when not connected to the computer? As I said above, they just may not be lit up.