as far as I know, it will. does your motherboard support 3.0? that is the most important part for pci-e 3.0 support. if that doesn't then it doesn't matter what you have. you will also need at least an ib cpu and a 3.0 vid card.
I'm using a corsair 750 that is around the same vintage and it works just fine for pci-e 3.0