IT's not an issue of which is faster, it's an issue ofg what bus speed your machine runs at. If you have a 133mhz bus, you need 133mhz ram. If you use 100mhz ram, it won't work (well, it might, but that's another issue). Similarly, if you have a 100mhz bus, you need 100mhz ram. You can use 133mhz ram, but it will just run at 100mhz.
Basically, choose ram that's at least as fast as your bus speed. If you choose ram that's too slow, you might have stability problems, or your machine might not boot at all. If you choose ram that's too fast, the extra performance jsut isn't used. It's like buying a racecar to drive around town, you can only go so fast on a 100mhz bus.