ive studied this some and also been to lectures on the subject.
basically, no one knows anything for sure about our climate/atmosphere and if it is a continuous, cyclical process of deteriorating and fixing itself. global warming is also a straw-man made by hippies and treehuggers. the world is much, much more massive than most people can even comprehend. as much industry as we produce still is not enough to cause enough heat transfer to make a massive impact world wide. im sure we didnt help, but realistically we have no clue whether or not this is a naturally occuring cycle and if we did anything to effect/change the process.
edit, i should also add this:
3O2 <=> 2O3 (oxygen in the upper atmosphere is constantly being converted to ozone and vice versa, it naturally occurs at that altitude and temperature)