The KT333 and KT266a are first cousins, and share most of their architecture, so heres the deal. You will get more performance, and if you are a gamer, you get significantly more performance. The PCI can handle 50 mhz (see sig below) without issues, but the cooling to the PCI and IDE devices must be adequate. Otherwise, it's instant re-partition and format time. I haven't seen below 43 mhz PCI for two years, and never had any issues.
My Gainward Ultra 650 XP (Golden Sample GF4-Ti4200, 128 mb), overclocked to 324/600, easily runs Unreal Tournament 2003, even at 86mhz AGP, (344 mhz data rate at AGP 4x). At about 180 mhz FSB (360 mhz data rate), I begin to have issues with AGP stability at ultra tight settings, and I have to lower the hardware settings to regain stability. The absolute lowest framerate is higher at this level, but the absolute maximum is lower, as the video card, or AGP bus is becoming saturated. A faster card might alleviate this, but it's just a guess. By 200 mhz FSB, everything (hardware) is at slowest timings, and settings, to stay stable.
Just aword of caution....Heat is the real enemy. You would be foolish to try cranking up the FSB without quality Video card cooling, CPU cooling, and certainly better case cooling. Go slowly, monitor temps, and test at each stage, for errors and stability.
Good luck!