Omg, how do i do this?

ManBearPig

Diamond Member
Sep 5, 2000
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A chemist uses a standard solution of 0.052 M sodium hydroxide (NaOH) to titrate 16.64 mL of hydrochloric acid (HCl), she finds that it requires 25.57 mL of the base to reach the end-point of the titration. What is the molarity of the acid solution ?

I thought it was m1*v1=m2*v2

but it apparantly doesnt work....any ideas?

 

soydios

Platinum Member
Mar 12, 2006
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I took Chem last year, here's what I remember (including significant figures at each step):

(0.02557 mL OH- solution) x (0.052 molar OH- solution) = 0.0013 moles OH-
(0.0013 moles OH-) = (0.0013 moles H+)
(0.0013 moles H+) / (0.01664 mL H+ solution) = 0.078 molar H+ solution
 

HaxorNubcake

Golden Member
Jun 23, 2004
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Originally posted by: soydios
I took Chem last year, here's what I remember (including significant figures at each step):

(0.02557 mL OH- solution) x (0.052 molar OH- solution) = 0.0013 moles OH-
(0.0013 moles OH-) = (0.0013 moles H+)
(0.0013 moles H+) / (0.01664 mL H+ solution) = 0.078 molar H+ solution

yeah same as my answer, i just kept all the numbers.

thats the same answer as m1v1=m2v2 which would make sense, but there might be some diff way to do it. I dunno chem was 2 years ago for me
 

gsethi

Diamond Member
Feb 28, 2002
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50mL of 0.2mol L-1 NaOH neutralised 20mL of sulfuric acid. Determine the concentration of the acid

1. Write the balanced chemical equation for the reaction
NaOH(aq) + H2SO4(aq) -----> Na2SO4(aq) + 2H2O(l)
2. Extract the relevant information from the question:
NaOH V = 50mL, M = 0.2M H2SO4 V = 20mL, M = ?
3. Check the data for consistency
NaOH V = 50 x 10-3L, M = 0.2M H2SO4 V = 20 x 10-3L, M = ?
4. Calculate moles NaOH
n(NaOH) = M x V = 0.2 x 50 x 10-3 = 0.01 mol
5. From the balanced chemical equation find the mole ratio
NaOH:H2SO4
2:1
6. Find moles H2SO4
NaOH: H2SO4 is 2:1
So n(H2SO4) = ½ x n(NaOH) = ½ x 0.01 = 5 x 10-3 moles H2SO4 at the equivalence point
7. Calculate concentration of H2SO4: M = n ÷ V
n = 5 x 10-3 mol, V = 20 x 10-3L
M(H2SO4) = 5 x 10-3 ÷ 20 x 10-3 = 0.25M or 0.25 mol L-1

Taken from: http://www.ausetute.com.au/titrcalc.html
Example 2