Joony, rolling your own power over Ethernet should be left for the EEs in the room. If you don't know what you're doing, don't try it. If you do know what you're doing, you should be okay.
IEEE 802.3af PoE is 350mA max @ 48V over standard cat5 cable plant. There is a fairly sophisticated level of protection against overcurrent (short et al.) conditions, including a PoE link sense that must be done in order to "negotiate" sending power down the port (that is to say, it is not powered by default, you have to do something to trigger the PoE injector to send). All this is there for good reasons, so if you're rolling your own you should think carefully about whether you should roll your own without the same protections.
The 3Com NetJack switches are cheap in-wall switches with pass-through ports that accept PoE, and you can use an outboard injector on the other side of a cable. This will allow you to have a remote PoE switch on a budget. I'd strongly urge you to use an off-the-shelf solution like this.