This unit is really what I prefer to call a fan SPLITTER. That is because it does NOT have any way to get power for its fans from the PSU directly, unlike what I prefer to call a fan HUB. So ALL the power for this unit must come only from the host header on the mobo, and that means its TOTAL load for all fans connected is limited to whatever the header can provide. Commonly that is 1.0 A max, but some mobo headers are different. In that respect, this unit makes it too easy to connect too many fans (10 ports available) if you fail to do your calculations from the specs of the fans you plug in. As an aside, I see that the unit MAY come also with a cable allowing you to power it from the PSU directly, and NOT from a mobo header. In this mode there is NO speed control by the mobo, but the limit on total current does not apply.)
OP's questions MAY imply a misunderstanding. On a 3- or 4-pin fan header the pin functions are: Pin #1 Ground, Pin #2 +VDC power supply, Pin #3 Speed signal (sent back to mobo). For a 4-pin one Pin #4 is the PWM signal. Any Splitter or Hub will return to the host header the speed signal from only ONE of its fans because that's all the header can deal with. On a unit with several cable "arms" as outputs, the simple way used to make this happen is that the male output connectors are missing Pin #3 on all but one output, so there can be no connection of "other" fans' speed signals. But on units like this NZXT one that look like circuit boards, and on closed boxes with side ports, the lone output that DOES send back its speed signal is marked in some way, and the design of the circuit inside is how the speeds of the "others" are NOT sent back. On many this is simply output Port #1. Sometimes it is labelled "CPU Fan", but you do NOT need to plug into that the CPU cooler if the Hub is used solely for case fans. So for this NZXT Grid unit you must plug into its Port #1 one of your fans to ensure the host header receives a speed signal from that. There is no question of "use all 3 pins" because the unit itself simply makes the speed connection back to the host header from ONLY its output Port #1.
Just a last note for both Splitters and Hubs. An important second function of any fan header is to monitor the speed signal it receives from its fans for NO signal, indicating fan FAILURE. A failure prompts a prominent message on your screen so you can deal with the problem. (In the particular case of failure of the fan on the CPU_FAN header, more drastic actions may be taken.) Since Splitters and Hubs return to the header only ONE fan's speed signal the header cannot monitor all the "others" for failure. Thus the user should check all fans from time to time to verify they all still are working.