It's the 12v line that means you need the extra molex.
Most people don't have a clue about their PSU's.
A generic 500w PSU is probably going to have the same 12v line as a 330w Antec PSU, probably 16~18A.
XBit says you need high 12v for the 6800U.
Most PSU's skimp on the 12v, so you need to ensure you can get good 12v power to the card, and molex connectors allow this (2 coming straight from the PSU means more chance of clean 12v power I would guess).
As shown, the GeForce 6800 Ultra doesn?t practically take any power through the AGP slot. The total consumption of the card on the 3.3v, 5v and 12v lines that go through the AGP is less than 5W. But the card consumes as much as 48.91W in the Burn mode through the 12v line of the additional power connector. The current in this line is 4.22 amperes, which is rather much even for the Molex 8981-04 connector.
(I wrote my comment before seeing the XBit labs comment saying almost the same thing).
Personally I think an Enermax woul dbe best for a 6800U, as they have either dual 12v rails, or a very high 12v rail (much higher than Antec's, at similar wattages).
330w Antec has 18A 12v rail, IIRC. The 350w Enermax has a 26A or thereabouts 12v rail, and the 320w Enermax has 2 rails totalling 24 A IIRC.