Question New tiny capacitors to be used on chip, using negative capacitance effect for large power density and energy density.

May 11, 2008
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I can remember the times we had great discussions about how Low-k and high-k dielectric materials and their effects for gate insulators affect the Field Effect Transistors.
The 2D shape and later the 3D shape of the gate from various switching elements like fets.
Repeatedly reading all the novel articles, desperately trying to understand the very serious (quantum mechanical) physics behind it.

Subjects like electron tunneling, causing leakage of charge from gates.
Fets used for storage of data. And how electron tunneling influences the stored bits that are stored as charges on fully insulated gates.
Programming such bits is actually forcing electrons through an insulator with a higher voltage.
And then trapping these electrons on the gate insulator which results as a stored and trapped gate charge if i remember correctly.
This all to get a Fet either in a conduct state or a non conducting state. Meaning storing a 0 or a 1.

Now a capacitor has been developed that has a very large power density and energy denstiy.
Read it at the provided links :

Small excerpt from the text :
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Tiny capacitors amp up energy storage.
Researchers developed miniaturized capacitors with 170 times higher power density that can be built directly into microchips to power them.
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Small excerpt from the text :
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In the ongoing quest to make electronic devices ever smaller and more energy efficient, researchers want to bring energy storage directly onto microchips, reducing the losses incurred when power is transported between various device components.
To be effective, on-chip energy storage must be able to store a large amount of energy in a very small space and deliver it quickly when needed – requirements that can’t be met with existing technologies.
...........
Capacitors are one of the basic components of electrical circuits but they can also be used to store energy. Unlike batteries, which store energy through electrochemical reactions, capacitors store energy in an electric field established between two metallic plates separated by a dielectric material. Capacitors can be discharged very rapidly when needed, allowing them to deliver power quickly, and they do not degrade with repeated charge-discharge cycles, giving them much longer lifespans than batteries. However, capacitors generally have much lower energy densities than batteries, meaning they can store less energy per unit volume or weight, and that problem only gets worse when you try to shrink them down to microcapacitor size for on-chip energy storage.
..........
Here, the researchers achieved their record-breaking microcapacitors by carefully engineering thin films of HfO2-ZrO2 to achieve a negative capacitance effect. Normally, layering one dielectric material on top of another results in an overall lower capacitance. However, if one of those layers is a negative-capacitance material, then the overall capacitance actually increases. In earlier work, Salahuddin and colleagues demonstrated the use of negative capacitance materials to produce transistors that can be operated at substantially lower voltages than conventional MOSFET transistors. Here, they harnessed negative capacitance to produce capacitors capable of storing greater amounts of charge, and therefore energy.
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soresu

Diamond Member
Dec 19, 2014
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Should be useful for DRAM, as I understand it, is capacitor and transistor-based.
Future DRAM research has already moved on from capacitor based device designs.

The new capacitorless direction makes scaling easier and multi level (3D) DRAM devices possible, so when they finally get to fabs it could be the biggest jump in memory in a very long time - especially as DRAM scaling has basically been at a standstill for years.
 

Doug S

Diamond Member
Feb 8, 2020
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Future DRAM research has already moved on from capacitor based device designs.

The new capacitorless direction makes scaling easier and multi level (3D) DRAM devices possible, so when they finally get to fabs it could be the biggest jump in memory in a very long time - especially as DRAM scaling has basically been at a standstill for years.

Do you have any links with information about this new approach? I hadn't heard anything about making DRAM without capacitors, other than all the "DRAM killer" technologies that come around every few years like NRAM, ReRAM, early Intel hype for what became Optane, and on and on.
 
May 11, 2008
22,175
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Permittivity also known as the dielectric constant is what is key here i think we can safely assume.

The text in this post is an example about ceramic capacitors has nothing to do with the newly developed "microchip" capacitor that is described in the first post.
But has todo all about electric fields, electric polarization and dipole moments.
But the text in the link explains greatly how those tiny ceramic capacitors can store so much charge.
Class 2 ceramic capacitors having dielectric constants AKA permittivity of value 500 up to 20000 and perhaps in current times even higher.

And for this newly developed capacitor, it is also all about creating a huge permittivity.
Although it is probably not an issue with on chip capacitors, it makes me wonder if there exists a DC bias effect.
And what about capacitance aging ?
If anybody knows, i am interested.

If you are interested in the deep basics of capacitors with respect to electric fields, electric polarization and dipole moments...
Then this book is a very good read :
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ABC of Capacitors English
Basic Principles, Characteristics and Capacitor Types - 1st Edition Order Code 744013

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Link about ceramic capacitors :
Small excerpt from the text :
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It is all about the dipoles

A lot of the magic of a capacitor comes from the dielectric material itself. Some people would describe a dielectric as an insulator that prevents the two electrodes from shorting.
That is true, but there is a bit more to dielectrics than just that. In a word, dipoles.
A quick Wikipedia search will show that a dielectric is that it is “an electrical insulator that can be polarized” with the application of an external electric field.
A piece of rubber is a great insulator, but it is a terrible dielectric. You can’t polarize rubber (very effectively).
It is the presence of those dipoles in the dielectric material that makes for an effective capacitor. KEMET uses two main types of materials for ceramic dielectrics.
Are you ready for some phrases that are going to take you back to chemistry class? First off is barium titanate (BaTiO3), which is used for our Class II/III dielectrics.
Those are our X5Rs and X7Rs, among others. Next is our calcium zirconate, that’s what we use in our class I dielectrics. That would be C0G and U2J.
This is where things get really interesting, calcium zirconate is paraelectric and barium titanate is ferroelectric.
Those properties have some similarities to the concepts of paramagnetism and ferromagnetism, which is introduced in early physics classes.


In ferroelectric materials, the dipoles are permanently present and will align themselves with an electric field.
In paraelectric materials, the dipoles appear spontaneously aligned with the application of an external electric field.
The dipoles created by class II dielectrics are a result of the materials and structure of the barium titanate itself.


Images taken from the link :

Image-5-class-1-and-2-physics-breakdown.png


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