Okay, Matlab is kind of weird when you first start out. Matlab is vector oriented.
Now, I'm assuming you want to plot the line between the points (1,1) and (5,5).
So, you have 2 x-coordinates and 2 y-coordinates.
Type this into Matlab:
x = [1 5]
y = [1 5]
The above tells Matlab that the x coordinates are 1 and 5 and the y coordinates are 1 and 5.
Now, tell Matlab to plot these data points by typing:
plot(x,y)