Yes.....never never connect anything to the -5V wire on the ATX connector.
The actual ATX connector wire(s) are the only place where you can get -5V from. -5V is meant to be supplied at very very low power (usually only a fraction of an amp), and should not be connected to any fans or anything like that. Even though you might be able to get +17V out of it (+12V) - (-5V)= 17VDC, your power supply would die quickly.
However, like the nice gentleman said above, you can get +7V out of the standard Molex 4 wire power connector. By connecting the fan between the +5 (red wire) and +12 (yellow wire), you will get a voltage differential of 7 Volts.