WOL is something very specific. It entails starting computer from OFF, and needs a specific Magic Packet.
For NAS, to be available 24/7, WOL is not a good solution.
Most modern computers can get out of Sleep mode (Sleep is Not Off) when there is any traffic knocking on its doors.
The problem is that the Wake from sleep does not have an official name and many providers call it Wake On LAN creating unneeded confusion.
In order to wake from sleep the OS and the NIC drivers needs to support the function.
Unfortunately some NIC drivers do not support it. Most of the old 939 (nVidia) computers with the Onboard NIC do support it.
In some computers, if it is Not supported through the drives, sometimes the trick is to do the opposite of NIC Power Saving.
I.e. Get the NIC out of the Sleep Power saving Loop.
By doing so the computer goes to sleep but the NIC stays up (the extra power consumption is probably no more than 1 Watt).
Usually, if the NIC is up it would react to Network request.
I know that it is confusing, but this is the misfortune of End-Users. The Vendors feels that they can do whatever they want to do to us as long as they manage to sell. (Draft_N is an example to it).