Ok, from your linux box, do an 'ifconfig eth0', and make sure you have the IP & netmask & gateway you are expecting. Then, from your other machine, try doing a ping of 192.xx.54, so see if maybe something is hokey on your little lan. It sounds like your card is somehow getting confused.
You might check to see if you have modconf available. I know it's available under Debian (One reason I REALLY like debian). Anyway, if you have modconf available, it really simplifies setting up your network card. Make sure you have your card configured the way you need it, and then reboot once to make sure your card and system comes up cleanly (no left over misconfiguring data). Then do your ifconfig eth0, and make sure everything is hokey-dokey.
You should be able to check logs in /var/logs/messages, and/or using the dmesg command. You can also get some handy information from /proc/....
One other thing you might need to look at with ISA cards is the isapnp utility. I'm pretty sure there is a ISAPNP howto on linuxdoc.org, and/or a FAQ for it.