<< You will see a spark. If the spark is big, you've got 'em reversed. >>
If there is question at ALL, you should NOT be jumping another car!
First, check the owners manual for instructions for any car made after about 1992. Many state do not jump the battery under ANY circumstances.
If at all possible, remove the battery from the car and charge it first. A slow charge preferably. Quick chargeing a dead battery can damage it permanently.
Using cables is an emergency procedure to be used only if there is no other option.
All batteries have the positive and negative terminals marked. It might be hard to see the battery surface, but you MUST determine which is which.
I recommend cables with a built in circuit breaker and switch. They have a light that alerts you if you make a mistake and will not let current flow if you get them on backasswards.
On cars with metal bumprs make sure they are not touching.
With the ignition switch in the off position on both cars. Attach the red cable to the positive terminal and the black to negative terminal on the good battery.
Now, look evrerything over and make sure it will be clear of the fanbelt and pulleys.
On the car with the weak battery, make sure the battery cables are clean and tight. Carefully attach the positice/red cable end to the positive terminal.
Now, there is no current flowing yet. Any time a lead-acid battery has current going through it it produces an explosive gas. You will make the final connection of the negative end of the jumper cable to the motor on an exposed bracket away from the battery. You will see a small spark if the circuit completes but by moving the connection away from the battery the chance of a battery explosion is much less. That exposed connection should be on the motor somewhere btw. Don't forget to check that the cables are clear of moving parts.
Now, start the car with the good battery. Keep it running slightly above idle for about 20 minutes. This charges the weak battery and makes starting the car with the weak one easier.
After starting, remove the cables in reverse order.
I would NEVER jump a motorcycle with a battery or car. Bike electronics are completely integrated and even a slight spark might do damage. Take the battery out and slow charge it. If it will not start the bike after being charged and you are sure everything else works, replace the battery with a new one.