What are you suppose to do then? Will it automatically write the whole file to the 2nd drive in the NAS transparently?
No. The other drive has its own folders. Or none. Depending on how you configure it.
There's a layer between you and the drive called the "file system." In pretty much every circumstance, a file can only be contained within a single file system.
Underlying file system is the "volume". This can be a partition on a disk, a whole disk, or some kind of multi-device volume - a RAID array, a spanned volume, whatever.
Let's say, as a for-instance: NAS, 2 6TB drives in JBOD mode. Drive1 and drive2. You format them both, and make a shared folder one drive1 called share1. That share1 folder exists within the 6TB file system on drive1, and that's all she wrote.
If you copy more than 6TB of data, you will run out of space on drive1 and the NAS will say "screw off, buddy." You would have to create another shared folder on drive2 (share2?) and copy data to that instead. It won't dynamically write data to both shared folders or file systems, since as far as the NAS is concerned, they are completely different entities. None of this is automatic. It's "just a bunch of disks" (JBOD) mode. They're pretty stupid and require you to manage them.
Now, if you did somehow create a spanned volume, or a RAID-0 volume (
neither of which is JBOD mode) then you would have a single 12TB volume. Writing >6TB of data would be fine, and the data would be stored on both disks as needed, since it would all be in the same file system. But, if one of the two drives fails, your file system would become corrupt and your data on both drives would go away.
The way around this is to create either a mirrored volume (which has half the capacity because it keeps copies of everything on both drives) or a striped volume with parity (which requires three or more drives.)