Another thing you need to consider is the mask. On a small LAN or a segment behind a router on a large LAN, the IP's need to have the same subnet mask scheme to communicate. For instance if one PC had 192.168.1.1 with a mask of 255.255.255.0, and another PC had 192.168.1.2 but a mask of 255.0.0.0, then, without another protocol to use, they would not communicate with each other.