http://www.geocities.com/sweaty2/tweak/windows/network.html
9. Set up gateway priority if having more than one
If you are able to connect to several gateways, it is possible to prioritize in which order the gateways should be searched for a certain address.
This is done by the Metric setting which is assigned to each gateway. The gateway with lowest Metric is the first to be searched(Default Gateway). Metric is the cost of using that gateway, and it will always use the one with the lowest cost first.
This can also be used if having more than one net-connection connecting so the same Network(Subnet) and they have different gateways. Example if using a wireless NIC and a standard NIC, then one can decide if it should use go through the Wireless NIC before using the Standard NIC by giving the Wireless NIC's gateway a lower metric.
To Setup the metric go to network settings and change the Internet Connection (TCP-IP)