I'm not quite sure how you ended up with this happening but I had this same problem, except the other way around, recently when I installed a second new copy of XP onto my freshly installed SATA drive.
The utility that helped me most (in XP, at least) is DiskPart, which you can run from a plain ol' command prompt while logged into XP (and 2K also, I think). The DiskPart in the Recovery a completely different program altogether, so steer clear of that one.
I'd give you step by step directions, but it seems like you'd have more fun doing it yourself, so hit up your nearest command prompt, type 'diskpart', and enjoy 😀
This is assuming, of course, that you can boot into XP... in the case that you can't, well, umm... do you have another box that you can burn a BartPE bootdisk from? :frown: