You have to clone it, not just copy the files, as you need the boot sector too. You can do it in Linux with dd, or download some freeware from the DOS days (Diskcopy?).
In "My Computer" or "Windows Explorer", highlight the "A" drive, right-click, choose "copy disk", select the same drive as the destination drive. Nothing special needed for a botable floppy.
If you might want to make future copies of the same disk, save it to an image file first. WinImage is good for that but it's shareware. There are freeware image file creators though that are dedicated to floppies.
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