I used to have that problem, and I found that steel wool worked pretty well. Of course, it was on a '78 Catalina, which was already 1/2 rust and 1/2 paint. Man, I miss that old boat.
My former landlord cut some branches off a tree which then proceeded to bleed sap all over the roof and hood of my car.
Getting it off the windshield was a pain.
No chemical worked to get it off the body except scratch pads which then left marks in the paint.
I had to use one of those micro-abressive paint restorers to make it look normal again.
That was just the hood. The stuff on the roof is still there.
Denatured alcohol. I used to work in a detail shop. I would wax after you are done, so plan on spending several hours washing, drying with chamois, denatured alcohol on tar, sap, etc. and then a good wax.
I would gently scrape it off with a razor blade without touching the paint and then use a paint cleaner to get the final thin layer off. Follow that up with a coat of wax.
I know that if you get pitch on your hands, butter or margarine (or any oil, I guess) will soften it so that it will wash off. Wonder if it would work on cars?
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