Leave PCIe locked at 33.3 for overclocking...this way you do not simultaneously OC your PCIe bus and destabilize the system.
Keep the RAM divider at 533 if you have one (if not then 677). This is to make sure that you don't OC your RAM too much and destabilize the system (RAM speed increases with CPU speed by formula:
Adjusted RAM Speed=(CPU MHz/Divider)*2
At stock speeds:
The 533 divider would equal 11, since (2800/11)*2=509 and 509 is the largest possible value <533.
The 667 divider would equal 9, since (2800/9)*2=622 and 622 is largest possible value <667.
If you OC'd to 3 GHZ your RAM speed using the 533 divider would now become (3000/11)*2=545.5 MHz...same with other dividers and speeds
Once you get to a stable CPU clock you can experiment with different RAM speeds/timings/voltages to boost performance even more.
You might have to adjust CPU voltages in order to get a stable OC. To do this, test your system at the OC'd speed using Prime95, Orthos, or SuperPi. If it's not stable, increase the CPU Voltage slightly and keep testing.
This post is far from complete in terms of OCing information. I suggest you google around and get a good understanding of the basics of overclocking.