you have to use algebra here...
say the alloy has x moles of Al per y moles of Zn, the formula being Al
xZn
y. This is for the entire sample, imagine the sample (as written on paper) as one big molecule

.
So, the big molecule has a mass of 0.2560 grams. Now, x is the amount of moles of Al, so x times the molar mass of Al is the mass of Al in that big molecule. y times the molar mass of Zn is the mass of the Zn in that big molecule. and mass of Al + mass of Zn = 0.2560 grams. This gives you ONE equation with respect to both x and y
Since you now have x moles of Al, you now need 3x moles of H+ ions for the first equation. And for Zn, you need 2y moles of H+ ions. This means on the RIGHT hand side of the equation, you need 1.5x moles of H2 gas for the first chemical equation, and y moles of H2 gas for the second.
remember that at STP, one mole of a gas takes up 1 L of space. so since you are at STP, there are 0.158 moles of H2 gas. This means:
1.5x + y = 0.007049166
Now you have ANOTHER equation involving x and y.
So, you have a system of 2 equations with 2 unknowns. Do some alegra, and solve for x and y. Since you are looking for % mass of Al and x times the molar mass of Al gives you the mass of Al, the mass of Al divided the mass of the big molecule (remember, this is what we are calling the sample) gives you the decimal form of the %. multiply now by 100 to get the %.
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