You don't want to move to Greenville. Its a small farming town only staying afloat thanks to the college. It is practically deserted during the summer, there's few/no tech jobs, and not a whole helluva lot to do. The only redeeming quality of it is the Halloween party, I hear it's quite legendary.
North Carolina is pretty decent. Wilmington is always fun, beach nearby. I live in Raleigh and like it. RTP for tons of tech jobs, lots of different areas to live to suit your taste.
Asheville is also nice. Small but spread out mountain town, downtown is cool, but housing costs are pretty high.
What do you want to know?
EDIT Should mention my parents moved to Greenville about four years ago and I lived there for two summers. That was quite enough