the Windows AHCI driver is raid compatible so you should be fine to set up the raid and flash the image over to it. Worst case is to run the recovery console and do a repair after the flash if you did have issue.
The other way would be to set to the bios to raid mode for the single drive and try a reboot. If issue arises try the repair as mentioned above. If a repair is needed.. save the new image for use after the array is built. If not then proceed onwards.
You should always secure erase a used SSD prior to reinstallation for resetting the controllers mapping and memory to factory fresh states. Many just reformat and reinstall which is usually fine but does not actually reset the controller in the same manner and instead relies on garbage collection to straighten out the mess.
So, just SE both drives to reset them, build the raid(64k stripes are decent all-around for an OS volume), and flash the backup image. Simple stuff once you do it a few times. Good Luck with it.