What case are you using? Is it a regular "single chamber" setup? And what kind of hardware do you have inside? What size are you fans - are they all the same model/size? In general, five fans is verging on overkill for most computers, going past the point where more air gets you noticeable cooling benefits, all the while creating more noise. If I were you (and your setup isn't something like an ultra-OCd X99 or AM3 platform with dual/tri SLI/Crossfire - i.e. pulling 800W+ under load), I'd step down to four fans - two intakes at the front, one exhaust in the rear and one in the top. I'd then adjust the setup so that the exhaust fans run slightly (~20-30%) slower than the intakes - either by using some sort of voltage limiter wire or controlling it through the BIOS/motherboard software.
The main point of positive pressure is to avoid dust being pulled in through cracks and openings in the case, while at the same time making sure all coolers always have sufficient airflow. Overdoing it doesn't make any real difference. Keep the fifth fan as a backup or for some other use.
Edit: damn, I had this thread open from this morning, and forgot that the case was in the topic title. I take it all your fans are 140mm? If not, the front takes three 120mm fans. Still, I stand by my advice for the 2+2 setup.