Welcome to the astronomy buff world.
Venus looks like a little phase. Like the moon.
I think it's in Gibbous right now. I really need to check.
With that Meade 125, if at a dark location, you should see some nebulosity in the pleiades.
You'll find it slightly NW of where Jupiter and Saturn are right now, it's a tight grouping of small stars. It kinda looks like a dipper. People commonly mistake it for being the little dipper.
Also, about 2-3 hours after Jupiter and Sat are high in the sky, the constellation Orion is up.
Look in the sword, and find the orion nebula. That's a pretty cool sight.
Have a good time with your scope. I live in the 'burbs of NYC and I don't get to see dark skies too often.
Oh, wait a couple of weeks until the moon is at first quarter. Now that is cool. The craters and stuff. Get friends in on looking at Saturn, people always thought I was putting a picture in the telescope of it. After convincing them, it always got a big WOW!