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Why the hell would it matter? I am sure that it does not change the cooling properties of the metal. And if it did, I really doubt it would cause any significant difference.
Well you can always use some metal polish to clean off the tarnish then wipe it w/ alcohol, rub AS5 on the surface of the heatsink, wipe it off w/ lint free cloth, and finally apply thin layer of AS5 on the CPU's core and put the HSF back on.
Theoretically tarnishing would affect temps since Cu-oxide is not as good of conductor as pure Cu. However, the heatsink has so much surface area that the Cu-oxide "poorness" doesnt really make it to the real picture.
Flatness more important than shininess. Most commercial HSs can use a good lapping for flatness and if it happens to make them shiny in the process, what the hey...
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