You mean XFree?
For Radeon 7500, you need XFree 4.2.0 at least.
Then, right after poweron, the Radeon should be detecting both monitors, and mirror the boot output on both. At least that's what my PowerColor RV2LE does.
Next, you need to modify your /etc/X11/XF86Config file to contain two almost identical "Device" sections, with "Screen 0" and "Screen 1" statements for the two heads. Complement with two "Monitor" and "Screen" sections, define the physical arrangement in the "ServerConfig" section, and there you go.
The lazy might want to start by moving the old XF86Config away, and running "X --configure" from the command line. That'll detect the dual head card and write a proper template XF86Config file.
Finally, you get to choose whether to use Xinerama (spread one logical display across all screens) or independent instances of X running on each monitor.
There is a HowTo document for all that as well.
www.xfree.org
regards, Peter