Air enters a power supply from the case and leaves it from the back.
This is done differently.
In most power supplies a fan mounted on the side of the PSU and facing the back of the case blows air out the back out of the PSU. So, the fan blows air out the PSU and out the case.
In some power supplies, a fan is installed inside the PSU that is on the side that is inside the case. This fan sucks air inside the PSU from the case. As a result, the air pressure inside the PSU is higher than the air pressure outside the case. Because of this pressure difference, air is pushed out the PSU and the case from the side that faces the back of the case. So, the fan sucks air into the PSU but pushes air out the case.
Some PSUs have both of these fans.
Either way, air enters the PSU from the case and leaves the PSU out the back.
Under no circumstance should air exit the PSU into the case!