Normally the "92mm" "big" fan on the bottom does suck air into the power supply, then the smaller 80mm blows out the back. (this is how my enermax is set up) IF they're both blowing out of the power supply it would seem they'd be fighting each other. There should be a path of air sucked from around your processer, through the bottom of the powersupply, and out the back of the case.
Also, on most heatsinks you want the fan to blow towards the heatsink, or into it. There are a few exceptions to the rule, such as the Alpha heatsinks, which are designed to have the air "pulled" through them.