I wrote a simple python script to analyze your posted Encrypted.txt. Here's some of the output:
occuring chars (ascii number):
[215, 254, 15, 249, 255, 229, 145, 223, 59, 239, 252, 127, 241, 206, 35, 47, 253, 242, 203, 168, 151, 107, 31, 247, 181, 154, 51, 175, 248, 63, 227, 158, 55, 191, 137, 111, 159, 228, 138, 226, 236, 133, 123, 140, 95, 230, 79, 155, 27, 231, 71, 139, 67, 153, 209, 177, 144, 134, 211, 143, 146, 91, 207, 251, 141, 156, 147, 75, 157, 43, 178, 150, 244, 136, 119, 219, 238, 39, 83, 221, 245, 250, 99, 182, 152, 237, 171, 187, 225, 192, 166, 179, 103, 115, 142, 148, 199, 234, 3, 172, 222, 23]
number of chars used in crypted alphabet: 102
max char = 255
min char = 3
char usage count:
[0, 0, 0, 3, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 0, 40, 0, 0, 0, 0, 0, 0, 0, 1, 0, 0, 0, 12, 0, 0, 0, 24, 0, 0, 0, 14, 0, 0, 0, 6, 0, 0, 0, 8, 0, 0, 0, 61, 0, 0, 0, 33, 0, 0, 0, 15, 0, 0, 0, 1, 0, 0, 0, 111, 0, 0, 0, 22, 0, 0, 0, 28, 0, 0, 0, 7, 0, 0, 0, 26, 0, 0, 0, 7, 0, 0, 0, 0, 0, 0, 0, 24, 0, 0, 0, 48, 0, 0, 0, 2, 0, 0, 0, 8, 0, 0, 0, 56, 0, 0, 0, 55, 0, 0, 0, 3, 0, 0, 0, 12, 0, 0, 0, 29, 0, 0, 0, 251, 0, 0, 0, 0, 0, 1, 23, 0, 25, 11, 26, 70, 46, 34, 1, 38, 55, 44, 25, 21, 3, 0, 50, 74, 11, 6, 111, 46, 11, 11, 75, 8, 0, 0, 0, 0, 0, 0, 1, 0, 3, 0, 0, 7, 2, 0, 0, 73, 0, 1, 4, 4, 0, 9, 5, 0, 0, 0, 0, 2, 0, 0, 0, 224, 1, 0, 0, 0, 0, 0, 0, 1, 0, 0, 0, 9, 0, 0, 1, 37, 0, 12, 0, 28, 0, 0, 0, 16, 0, 0, 0, 3, 0, 13, 1, 250, 0, 10, 62, 57, 73, 51, 89, 66, 0, 0, 2, 0, 5, 6, 4, 34, 0, 1, 21, 0, 15, 14, 0, 104, 108, 272, 6, 11, 9, 165, 407, 1648]
interesting that 0xFF (255) occurs so often, and also 0xFE. also, early on, characters only occur that are (mod 4) - 1... but the frequency of use generally increases as you go up in the ASCII table.
notice how there's 102 characters occuring in the crypted alphabet.. so that rules out a 1:1 relationship algorithm (there's only about 62 ASCII characters that are are really used in plain text).
edit: next step is to do similar analysis by 2-byte pairs or 4-byte words rather than single bytes.