I'm having trouble visualizing the framing you're describing, a line drawing would be helpful.
For the hangers and hardware, be sure it's ICQ rated or it will rust out very rapidly.
I ended up using 2X8s. I connected a ledger to the house with tapcons on the block, then used that as a nailer for the first cross joist. The ledger will serve as a mounting point for j-channel for the bottom row of vinyl siding along the deck floor. Prior to that, I had a metal starter row 5" lower.
I basically made a few 10X16 boxes (spanning 115") with posts between them for support in the middle...then drove galvanized carriage bolts through them. On the outside edge of the deck, I used 4x4 posts and bolts as well.
I'm using metal hangers and galvanized hanger nails (1.5") and 12d galvanized 3 1/4" nails where I can for extra support. So far the deck has a little bit of bounce to it, but it will be better once I get the decking boards on it. I figure if I'm not happy after decking 25% of the top surface, I can always try sliding a few posts on their side underneath the center of the deck sections midway and block it to break the span...without too much extra work.... I just didn't want to do more permanent posts or break the spans up to require more cuts and materials. I should be able to finish this 16'X20' composite deck project under $2200 by the time I'm finished.