You can easuly test which is the better configuration by testing the two different options yourself. Theoretically speaking, when the fan is sucking, air from the region around the heatsink enters the heatsink and then exhausts from the top of the fan away from the heatsink towards the case, right infront of the place where usually one can mount the exhaust fan in the case rear, and then it directly goes out of the case. Moreover, when air is sucked in from around the heatsink, it forces the air surrounding the capacitors close to the cpu socket and the air around the chipset to move towards the heatsink, thus cooling the capacitors. On the other hand if you set up the fan to blow, it takes colder air from a region that usually the exhaust fan pulls out, i.e the two fans almost work against each other. Then the air is blown on the heatsink, then some of the heated up air ends up flowing around the capasitors and the chipset and heating them up. Of course all of the above is purely theoretical.